Health and Safety Data

MATERIAL SAFETY DATA SHEET

Section 3, Composition/information on ingredients:
3.2 Mixtures:
Name                                        Percentage         CAS                  EC Number  
     
Hydrocarbons C10-C13
aliphatic                                   30%-60%    64742-48-9        918-481-9          
Hazard Statements*  H304

Zirconium Drier 18%              <1%                     –                                 –              
Hazard Statements*  H226, H317

Hydroxyphenyl benzotriazole  <1%             –                         400-830-7   
Hazard Statements*  H317, H411

(*) For full text, see Section 16

Section 4. First aid measures:
4.1 Description of first aid measures:
Eyes:
Contact lenses should be removed. Irrigate copiously with clean fresh water for at least 10 minutes, holding the eyelids apart and seek medical advice.
Skin:
Remove contaminated clothing. Wash skin thoroughly with soap and water or use a   prorietary skin cleaner. Do NOT use solvents or thinners. Obtain medical attention if irritation persists.
Ingestion:
Wash out mouth with water. Obtain medical attention urgently. Keep at rest. DO NOT induce vomiting.
Inhalation:
Remove patient to fresh air. Keep the patient warm and at rest. If respiration stops or shows signs of failing, administer artificial respiration. Obtain medical aid urgently.
Other:
In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.
4,2 Most important symptoms and effects, both acute and delayed:
Dizziness. Headache.
4.3 Indication of any immediate medical attention and special traetment needed:
Immediate/special treatment: Not applicable.

Section 5. Fire fighting measures:
5.1 Extinguishing media:
Use carbon dioxide, dry chemical, sand or earth for small fires. For large fires use alcohol type foam or water spray. Do not use water jets. Cool closed containers with water spray.
5.2 Special hazards arising from the substance or mixture:
Formation of toxic gases is possible in case of fire.
5.3 Advice for firefighters:
Protective equipment:
Mouth respiratory protective device.

Section 6. Accidental release measures:
6.1 Personal precautions, protective equipment and emergency procedures:
Personal precautions:
Keep away from sources of ignition and ensure adequate ventilation. Wear protective equipment.
6.2 Environmental precautions:
Do not allow to enter sewers, drains or watercourses.
6.3 Methods and material for containment and cleaning up:
Contain and collect spillage with non-combustible absorbant materials, (e.g. sand, earth, vermiculite, diatomaceous earth), ensure adequate ventilation.
Dispose of in accordance with the waste regulations (See section 13). Clean the spill area preferably with a detergent. Avoid the use of solvents.

Section 7. Handling and storage:
7.1 Precautions for safe handling:
Keep the container tightly closed. Exclude all sources of heat, sparks and open flame. 
The accumulation of contaminated rags may result in spontaneous combustion.
7.2 Conditions for safe storage, including any incompatibilities:
Store between 5 and 25 degrees C in a dry, well ventilated place.
Containers which are opened should be properly sealed and kept upright to prevent leakage.
7.3 Specific end use(s):
No further relevant information available.

Section 8. Exposure controls/personal protection:
8.1 Control parameters:
Ingredients with limit values that require monitoring at the workplace:
Aliphatic hydrocarbons C10-C13, TWA (8h), 1200 mg/m3.
8.2 Exposure controls:
Engineering Measures:
Provide adequate ventilation.
Personal protective equipment:
Avoid inhaling vapour. Avoid contact with skin and eyes. Wear impervious gloves and/or solvent resistant barrier cream. Ensure good ventilation.
Respiratory:
Not necessary if room is well ventilated. Suitable respiratory protective equipment should be worn when this product is sprayed if ventilation is insufficient.
Hand:
Wear protective gloves. When skin exposure may occur, advice should be sought from glove suppliers on appropriate types. barrier creams may help to protect exposed areas of skin but are not substitutes for full physical protection. Do not apply barrier cream once exposed.
Eye:
If risk of splashing: Eye protection designed to protect against liquid splashes should be worn.
Other:
Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner.

Section 9. Physical and chemical properties:
Section 9.1 Information on basic phsical and chemical properties:
Appearance:
Liquid.
Odour:
Characteristic mild hydrocarbon solvent.
Colour:
Pale reddish
Flash Point:
62 °C
Autoflammability:
230-300 deg C
Initial boiling point range:
180 deg C
Lower explosion limit:
0.7% by volume.
Specific Gravity:
0.83 – 0.85.
Solubility:
Immiscible with water.
Viscosity:
Kinematic at 20 deg C:  25-35s
Solvent content, VOC (EC):
<500g/l (VOC max Cat A/i (2010)= 500g/l)
Section 9.2. Other information:
No further relevant information.

Section 10. Stability and reactivity:
Stability:
Stable under the recommended storage and handling conditions.
Conditions to avoid:
Prevent exposure to  heat, flames or sources of ignition.
Materials to avoid:
Keep away from strong oxidising agents and strongly acidic materials.
Hazardous decomposition products:
In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and oxides of nitrogen may be produced.
Additional information:
Wash any cloths impregnated with this product immediately after use in soapy water and dispose of safely outside: There is a possiblility of self-combustion.

Section 11. Toxicological information:
11.1. Information on toxicological effects:
Acute oral toxicity:
Low toxicity: LD50 >5000mg/kg
Acute dermal toxicity:
Low toxicity: LD50 >5000mg/kg
Acute inhalation toxicity:
Low toxicity: LC50 greater that near saturated vapour concentration / 4 hours, rat.
Skin corrosion/irritation:
Long or repeated contact with the skin may cause dermatitis due to the degreasing effect of the solvent.
Serious eye damage/irritation:
Expected to be non irritating to eyes.
Respiratory irritation:
Not expected to be a respiratory irritant.
Respiratory or skin sensitisaton:
Not a skin sensitiser.
Aspiration Hazard:
Based on available information, the classification criteria are not met.
Germ cell mutagenicity:
Not mutagenic.
Carcinogenicity:
Not expected to be carcinogenic.
Reproductive and developmental toxicity:
Not expected to be a developmental toxicant.
Not expected to impair fertility.
Specific target organ toxicity – single exposure:
Not applicable.
Specific target organ toxicity – repeated exposure:
Basd on available information, the classification criteria are not met.

Section 12. Ecological information:
12.1, Toxicity;
12.1.2. Mixtures:
No aquatic toxicity data available for the mixture.
12.2. Persistance and degradability:
No information available.
12.3. Bioaccumaulative potential:
No information available.
12.4. Mobility in soil:
No information available.
12.5. Results of PBT and vPvB assessment:
Not identified as a PBT or vPvB substance.
12.6. Other adverse effects:
No information available.

Section 13. Disposal considerations:
13.1 Waste treatment methods:
Disposal methods:
Transfer any hazardous waste into suitable containers for subsequent disposal. Dispose of any hazardous waste in accordance with waste disposal or water authority regulations. Do not dump indiscriminately.
Material disposal:
Do not allow to enter drains or watercourses or dispose of where ground or surface waters may be affected.
Dispose of waste and other residues in accordance with local authority requirements. Contact specialist disposal companies.

Section 14. Transport information:
This product does not require a classification for transport, therefore 14.1, 14.2, 14.3, 14.4, 14.5, 14.6 and 14.7 do not apply.
14.1, U.N. number: void
14.2. Proper shipping name: void
14.3. Transport hazard class(es): void
14.4. Packing group: void
14.5. Environmental Hazards: void
14.6 Special precautions for user: void
14.7, Transport in bulk according to annex II of Marpol and the IBC code: not applicable.

Section 15: Regulatory information:
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture:
VOC (EC): <500g/l (VOC max Cat A/i (2010)= 500g/l).
15.2. Chemical safety assessment:
A chemical safety assessment has not been carried out.

Section 16. Other information:
Relevant phrases/ phrases used in Sections 2 and 3:
H304: May be fatal if swallowed and enters airways.
H317: May cause an allergic skin reaction.
H226: Flammable liquid and vapour.
H411: Toxic to aquatic life with long lasting effects.
P102: Keep out of reach of children.
P262: Do not get in eyes, on skin, or on clothing.

Other information:
The information contained in this safety data sheet is provided in accordance with the requirements of the Regulation EC1272 (2008).

Revision details:
V2.10-10-2020.

Legal disclaimer:
The information contained in this safety data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health, safety and environmental aspects of the product and should not be construed as any guarantee of technical performance or suitability for particular applications.
As the specific conditions of use of the product are outside the suppliers control, the user is responsible for ensuring that the requirements of relevant legislation are complied with.